Nitrogen fixation catalyzed by ferrocene-substituted dinitrogen-bridged dimolybdenum–dinitrogen complexes: unique behavior of ferrocene moiety as redox active site

A series of dinitrogen-bridged dimolybdenum–dinitrogen complexes bearing metallocene-substituted PNP-pincer ligands is synthesized by the reduction of the corresponding monomeric molybdenum–trichloride complexes under 1 atm of molecular dinitrogen. Introduction of ferrocene as a redox-active moiety...

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Detalles Bibliográficos
Autores principales: Kuriyama, Shogo, Arashiba, Kazuya, Nakajima, Kazunari, Tanaka, Hiromasa, Yoshizawa, Kazunari, Nishibayashi, Yoshiaki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707465/
https://www.ncbi.nlm.nih.gov/pubmed/29218165
http://dx.doi.org/10.1039/c5sc00545k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707465/
https://www.ncbi.nlm.nih.gov/pubmed/29218165
http://dx.doi.org/10.1039/c5sc00545k

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