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Nitrogen fixation catalyzed by ferrocene-substituted dinitrogen-bridged dimolybdenum–dinitrogen complexes: unique behavior of ferrocene moiety as redox active site
A series of dinitrogen-bridged dimolybdenum–dinitrogen complexes bearing metallocene-substituted PNP-pincer ligands is synthesized by the reduction of the corresponding monomeric molybdenum–trichloride complexes under 1 atm of molecular dinitrogen. Introduction of ferrocene as a redox-active moiety...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707465/ https://www.ncbi.nlm.nih.gov/pubmed/29218165 http://dx.doi.org/10.1039/c5sc00545k |