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Soft hydrogen bonds to alkenes: the methanol–ethene prototype under experimental and theoretical scrutiny

An FTIR spectroscopic study of the elusive hydrogen-bonded methanol–ethene complex, the most elementary example for weak intermolecular alcohol hydrogen bonding to a π cloud, is presented. By isolating the complex in a supersonic jet, the rigorous comparability to high-level quantum chemical calcula...

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Detalles Bibliográficos
Autores principales: Heger, Matthias, Mata, Ricardo A., Suhm, Martin A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707488/
https://www.ncbi.nlm.nih.gov/pubmed/29218143
http://dx.doi.org/10.1039/c5sc01002k