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Assessing the exchange coupling in binuclear lanthanide(iii) complexes and the slow relaxation of the magnetization in the antiferromagnetically coupled Dy(2) derivative

We report here the synthesis and the investigation of the magnetic properties of a series of binuclear lanthanide complexes belonging to the metallacrown family. The isostructural complexes have a core structure with the general formula [Ga(4)Ln(2)(shi(3–))(4)(Hshi(2–))(2)(H(2)shi(–))(2)(C(5)H(5)N)(...

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Detalles Bibliográficos
Autores principales: Chow, Chun Y., Bolvin, Hélène, Campbell, Victoria E., Guillot, Régis, Kampf, Jeff W., Wernsdorfer, Wolfgang, Gendron, Frédéric, Autschbach, Jochen, Pecoraro, Vincent L., Mallah, Talal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707489/
https://www.ncbi.nlm.nih.gov/pubmed/29218180
http://dx.doi.org/10.1039/c5sc01029b