Mechanism of the cooperative Si–H bond activation at Ru–S bonds

The nature of the hydrosilane activation mediated by ruthenium(ii) thiolate complexes of type [(R(3)P)Ru(SDmp)](+)[BAr(F)(4)](–) is elucidated by an in-depth experimental and theoretical study. The combination of various ruthenium(ii) thiolate complexes and tertiary hydrosilanes under variation of t...

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Detalles Bibliográficos
Autores principales: Stahl, Timo, Hrobárik, Peter, Königs, C. David F., Ohki, Yasuhiro, Tatsumi, Kazuyuki, Kemper, Sebastian, Kaupp, Martin, Klare, Hendrik F. T., Oestreich, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707498/
https://www.ncbi.nlm.nih.gov/pubmed/29218203
http://dx.doi.org/10.1039/c5sc01035g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707498/
https://www.ncbi.nlm.nih.gov/pubmed/29218203
http://dx.doi.org/10.1039/c5sc01035g

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