Charge transfer versus molecular conductance: molecular orbital symmetry turns quantum interference rules upside down

Destructive quantum interference has been shown to strongly reduce charge tunneling rates across molecular bridges. The current consensus is that destructive quantum interference occurs in cross-conjugated molecules, while linearly conjugated molecules exhibit constructive interference. Our experime...

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Detalles Bibliográficos
Autores principales: Gorczak, Natalie, Renaud, Nicolas, Tarkuç, Simge, Houtepen, Arjan J., Eelkema, Rienk, Siebbeles, Laurens D. A., Grozema, Ferdinand C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707500/
https://www.ncbi.nlm.nih.gov/pubmed/29218186
http://dx.doi.org/10.1039/c5sc01104c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707500/
https://www.ncbi.nlm.nih.gov/pubmed/29218186
http://dx.doi.org/10.1039/c5sc01104c

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