Thorium–ligand multiple bonds via reductive deprotection of a trityl group

Reaction of [Th(I)(NR(2))(3)] (R = SiMe(3)) (2) with KECPh(3) (E = O, S) affords the thorium chalcogenates, [Th(ECPh(3))(NR(2))(3)] (3, E = O; 4, E = S), in moderate yields. Reductive deprotection of the trityl group from 3 and 4 by reaction with KC(8), in the presence of 18-crown-6, affords the tho...

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Detalles Bibliográficos
Autores principales: Smiles, Danil E., Wu, Guang, Kaltsoyannis, Nikolas, Hayton, Trevor W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707506/
https://www.ncbi.nlm.nih.gov/pubmed/29218160
http://dx.doi.org/10.1039/c5sc01248a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707506/
https://www.ncbi.nlm.nih.gov/pubmed/29218160
http://dx.doi.org/10.1039/c5sc01248a

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