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Thorium–ligand multiple bonds via reductive deprotection of a trityl group
Reaction of [Th(I)(NR(2))(3)] (R = SiMe(3)) (2) with KECPh(3) (E = O, S) affords the thorium chalcogenates, [Th(ECPh(3))(NR(2))(3)] (3, E = O; 4, E = S), in moderate yields. Reductive deprotection of the trityl group from 3 and 4 by reaction with KC(8), in the presence of 18-crown-6, affords the tho...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707506/ https://www.ncbi.nlm.nih.gov/pubmed/29218160 http://dx.doi.org/10.1039/c5sc01248a |