Cargando…

Iron catalyzed CO(2) hydrogenation to formate enhanced by Lewis acid co-catalysts

A family of iron(ii) carbonyl hydride complexes supported by either a bifunctional PNP ligand containing a secondary amine, or a PNP ligand with a tertiary amine that prevents metal–ligand cooperativity, were found to promote the catalytic hydrogenation of CO(2) to formate in the presence of Brønste...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Yuanyuan, MacIntosh, Alex D., Wong, Janice L., Bielinski, Elizabeth A., Williard, Paul G., Mercado, Brandon Q., Hazari, Nilay, Bernskoetter, Wesley H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5707511/
https://www.ncbi.nlm.nih.gov/pubmed/29218198
http://dx.doi.org/10.1039/c5sc01467k