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Mechanism of Cobalt-Catalyzed CO Hydrogenation: 1. Methanation
[Image: see text] The mechanism of CO hydrogenation to CH(4) at 260 °C on a cobalt catalyst is investigated using steady-state isotopic transient kinetic analysis (SSITKA) and backward and forward chemical transient kinetic analysis (CTKA). The dependence of CH(x) residence time is determined by (12...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2017
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5716442/ https://www.ncbi.nlm.nih.gov/pubmed/29226009 http://dx.doi.org/10.1021/acscatal.7b02757 |