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Determining the Surface Structure of Silicated Alumina Catalysts via Isotopic Enrichment and Dynamic Nuclear Polarization Surface-Enhanced NMR Spectroscopy

[Image: see text] Isotopic enrichment of (29)Si and DNP-enhanced NMR spectroscopy are combined to determine the detailed surface structure of a silicated alumina catalyst. The significant sensitivity enhancement provided by DNP is vital to the acquisition of multinuclear and multidimensional experim...

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Detalles Bibliográficos
Autores principales: Rankin, Andrew G. M., Webb, Paul B., Dawson, Daniel M., Viger-Gravel, Jasmine, Walder, Brennan J., Emsley, Lyndon, Ashbrook, Sharon E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5722451/
https://www.ncbi.nlm.nih.gov/pubmed/29234484
http://dx.doi.org/10.1021/acs.jpcc.7b08137