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Fatty Acid Chain Shortening by a Fungal Peroxygenase
A recently discovered peroxygenase from the fungus Marasmius rotula (MroUPO) is able to catalyze the progressive one‐carbon shortening of medium and long‐chain mono‐ and dicarboxylic acids by itself alone, in the presence of H(2)O(2). The mechanism, analyzed using H(2) (18)O(2), starts with an α‐oxi...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5725704/ https://www.ncbi.nlm.nih.gov/pubmed/29083064 http://dx.doi.org/10.1002/chem.201704773 |