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Selective Activation of C−H Bonds in a Cascade Process Combining Photochemistry and Biocatalysis

Selective oxyfunctionalizations of inert C−H bonds can be achieved under mild conditions by using peroxygenases. This approach, however, suffers from the poor robustness of these enzymes in the presence of hydrogen peroxide as the stoichiometric oxidant. Herein, we demonstrate that inorganic photoca...

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Detalles Bibliográficos
Autores principales: Zhang, Wuyuan, Burek, Bastien O., Fernández‐Fueyo, Elena, Alcalde, Miguel, Bloh, Jonathan Z., Hollmann, Frank
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5725739/
https://www.ncbi.nlm.nih.gov/pubmed/28994504
http://dx.doi.org/10.1002/anie.201708668