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Total Syntheses of (−)-Majucin and (−)-Jiadifenoxolane A, Complex Majucin-Type Illicium Sesquiterpenes

[Image: see text] We report the first chemical syntheses of both (−)-majucin and (−)-jiadifenoxolane A via 10 net oxidations from the ubiquitous terpene (+)-cedrol. Additionally, this approach allows for access to other majucin-type sesquiterpenes, like (−)-jiadifenolide, (−)-jiadifenin, and (−)-(1R...

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Detalles Bibliográficos
Autores principales: Condakes, Matthew L., Hung, Kevin, Harwood, Stephen J., Maimone, Thomas J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5729088/
https://www.ncbi.nlm.nih.gov/pubmed/29148748
http://dx.doi.org/10.1021/jacs.7b11493