Side-on coordination of boryl and borylene complexes to cationic coinage metal fragments

The M-(η(2)-BMn) complex [(η(5)-C(5)H(5))(OC)(2)Mn{μ-B(Cl)(tBu)Au(PPh(3))}] (2) can be functionalized via halide substitution reactions to afford isostructural complexes [(η(5)-C(5)H(5))(OC)(2)Mn{μ-B(R)(tBu)Au(PPh(3))}] (R = Ph, CCPh and NCS). It also reacts with coinage metal complexes [MCl(PPh(3))...

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Detalles Bibliográficos
Autores principales: Braunschweig, Holger, Radacki, Krzysztof, Shang, Rong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5729409/
https://www.ncbi.nlm.nih.gov/pubmed/29403636
http://dx.doi.org/10.1039/c5sc00211g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5729409/
https://www.ncbi.nlm.nih.gov/pubmed/29403636
http://dx.doi.org/10.1039/c5sc00211g

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