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Side-on coordination of boryl and borylene complexes to cationic coinage metal fragments
The M-(η(2)-BMn) complex [(η(5)-C(5)H(5))(OC)(2)Mn{μ-B(Cl)(tBu)Au(PPh(3))}] (2) can be functionalized via halide substitution reactions to afford isostructural complexes [(η(5)-C(5)H(5))(OC)(2)Mn{μ-B(R)(tBu)Au(PPh(3))}] (R = Ph, CCPh and NCS). It also reacts with coinage metal complexes [MCl(PPh(3))...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5729409/ https://www.ncbi.nlm.nih.gov/pubmed/29403636 http://dx.doi.org/10.1039/c5sc00211g |