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A bottom up approach towards artificial oxygenases by combining iron coordination complexes and peptides

Supramolecular systems resulting from the combination of peptides and a chiral iron coordination complex catalyze asymmetric epoxidation with aqueous hydrogen peroxide, providing good to excellent yields and high enantioselectivities in short reaction times. The peptide is shown to play a dual role;...

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Detalles Bibliográficos
Autores principales: Cussó, Olaf, Giuliano, Michael W., Ribas, Xavi, Miller, Scott J., Costas, Miquel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5734052/
https://www.ncbi.nlm.nih.gov/pubmed/29270284
http://dx.doi.org/10.1039/c7sc00099e