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A bottom up approach towards artificial oxygenases by combining iron coordination complexes and peptides
Supramolecular systems resulting from the combination of peptides and a chiral iron coordination complex catalyze asymmetric epoxidation with aqueous hydrogen peroxide, providing good to excellent yields and high enantioselectivities in short reaction times. The peptide is shown to play a dual role;...
Autores principales: | Cussó, Olaf, Giuliano, Michael W., Ribas, Xavi, Miller, Scott J., Costas, Miquel |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5734052/ https://www.ncbi.nlm.nih.gov/pubmed/29270284 http://dx.doi.org/10.1039/c7sc00099e |
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