Metal-free, Regio-, and Stereo-Controlled Hydrochlorination and Hydrobromination of Ynones and Ynamides

[Image: see text] We developed an atom-economical and metal-free method for the regio- and stereo-selective hydrohalogenation of ynones and ynamides using easy to handle DMPU/HX (X = Br or Cl) reagents. The reaction operates under mild conditions and a range of functional groups is well tolerated. W...

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Detalles Bibliográficos
Autores principales: Zeng, Xiaojun, Lu, Zhichao, Liu, Shiwen, Hammond, Gerald B., Xu, Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5735994/
https://www.ncbi.nlm.nih.gov/pubmed/29166765
http://dx.doi.org/10.1021/acs.joc.7b02257

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5735994/
https://www.ncbi.nlm.nih.gov/pubmed/29166765
http://dx.doi.org/10.1021/acs.joc.7b02257

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