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Sixteen isostructural phosphonate metal-organic frameworks with controlled Lewis acidity and chemical stability for asymmetric catalysis
Heterogeneous catalysts typically lack the specific steric control and rational electronic tuning required for precise asymmetric catalysis. Here we demonstrate that a phosphonate metal–organic framework (MOF) platform that is robust enough to accommodate up to 16 different metal clusters, allowing...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5736719/ https://www.ncbi.nlm.nih.gov/pubmed/29259195 http://dx.doi.org/10.1038/s41467-017-02335-0 |