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Catalytic asymmetric synthesis of a nitrogen heterocycle through stereocontrolled direct photoreaction from electronically excited state

The reactivity of photoexcited molecules has been extensively studied for decades but until today direct bond-forming reactions of such excited states in a catalytic and asymmetric fashion are restricted to the synthesis of cyclobutanes via [2 + 2] photocycloadditions. Herein, we demonstrate a previ...

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Detalles Bibliográficos
Autores principales: Huang, Xiaoqiang, Li, Xinyao, Xie, Xiulan, Harms, Klaus, Riedel, Radostan, Meggers, Eric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5740077/
https://www.ncbi.nlm.nih.gov/pubmed/29269853
http://dx.doi.org/10.1038/s41467-017-02148-1