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Catalytic asymmetric synthesis of a nitrogen heterocycle through stereocontrolled direct photoreaction from electronically excited state
The reactivity of photoexcited molecules has been extensively studied for decades but until today direct bond-forming reactions of such excited states in a catalytic and asymmetric fashion are restricted to the synthesis of cyclobutanes via [2 + 2] photocycloadditions. Herein, we demonstrate a previ...
Autores principales: | Huang, Xiaoqiang, Li, Xinyao, Xie, Xiulan, Harms, Klaus, Riedel, Radostan, Meggers, Eric |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5740077/ https://www.ncbi.nlm.nih.gov/pubmed/29269853 http://dx.doi.org/10.1038/s41467-017-02148-1 |
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