S(E)2 reaction in noncarbon system: Metal-halide catalysis for dehydrogenation of ammonia borane

An electrophilic substitution (S(E)) reaction of BN isosteres has been investigated for the dehydrogenation of ammonia borane (AB) by metal chlorides (MCl(2)) using various ab initio calculations. In contrast to the typical S(E) reaction occurring at the carbon atom, the nitrogen atom in AB serves a...

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Detalles Bibliográficos
Autores principales: Pai, Sung Jin, Han, Sang Soo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: National Academy of Sciences 2017
Materias:
Physical Sciences
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5748185/
https://www.ncbi.nlm.nih.gov/pubmed/29229814
http://dx.doi.org/10.1073/pnas.1712137115

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5748185/
https://www.ncbi.nlm.nih.gov/pubmed/29229814
http://dx.doi.org/10.1073/pnas.1712137115

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