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Conformational preferences of α-fluoroketones may influence their reactivity

Fluorine has been shown in many cases to impart specific and predictable effects on molecular conformation. Here it is shown that these conformational effects may have an influence on reactivity through studying the relative reactivity of various α-halogenated ketones towards borohydride reduction....

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Detalles Bibliográficos
Autor principal: Pattison, Graham
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5753061/
https://www.ncbi.nlm.nih.gov/pubmed/29564019
http://dx.doi.org/10.3762/bjoc.13.284