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Conformational preferences of α-fluoroketones may influence their reactivity
Fluorine has been shown in many cases to impart specific and predictable effects on molecular conformation. Here it is shown that these conformational effects may have an influence on reactivity through studying the relative reactivity of various α-halogenated ketones towards borohydride reduction....
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Beilstein-Institut
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5753061/ https://www.ncbi.nlm.nih.gov/pubmed/29564019 http://dx.doi.org/10.3762/bjoc.13.284 |