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Hydrogenolysis of C−O Chemical Bonds of Broad Scope Mediated by a New Spherical Sol–Gel Catalyst

The new spherical sol–gel hybrid material SiliaCat Pd(0) selectively mediates the hydrogenolysis of aromatic alcohols, aldehydes, and ketones by using an ultralow catalytic amount (0.1 mol % Pd) under mild reaction conditions. The broad reaction scope as well as the catalyst's superior activity...

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Detalles Bibliográficos
Autores principales: Pandarus, Valerica, Ciriminna, Rosaria, Gingras, Geneviève, Béland, François, Pagliaro, Mario, Kaliaguine, Serge
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5754550/
https://www.ncbi.nlm.nih.gov/pubmed/29318100
http://dx.doi.org/10.1002/open.201700185