Hydrogenolysis of C−O Chemical Bonds of Broad Scope Mediated by a New Spherical Sol–Gel Catalyst

The new spherical sol–gel hybrid material SiliaCat Pd(0) selectively mediates the hydrogenolysis of aromatic alcohols, aldehydes, and ketones by using an ultralow catalytic amount (0.1 mol % Pd) under mild reaction conditions. The broad reaction scope as well as the catalyst's superior activity...

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Detalles Bibliográficos
Autores principales: Pandarus, Valerica, Ciriminna, Rosaria, Gingras, Geneviève, Béland, François, Pagliaro, Mario, Kaliaguine, Serge
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5754550/
https://www.ncbi.nlm.nih.gov/pubmed/29318100
http://dx.doi.org/10.1002/open.201700185
Descripción
Sumario:The new spherical sol–gel hybrid material SiliaCat Pd(0) selectively mediates the hydrogenolysis of aromatic alcohols, aldehydes, and ketones by using an ultralow catalytic amount (0.1 mol % Pd) under mild reaction conditions. The broad reaction scope as well as the catalyst's superior activity and pronounced stability open the route to green and convenient reductive deoxygenation processes of primary synthetic relevance in chemical research as well as in the fine chemical and petrochemical industries.

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