Hydrogenolysis of C−O Chemical Bonds of Broad Scope Mediated by a New Spherical Sol–Gel Catalyst

The new spherical sol–gel hybrid material SiliaCat Pd(0) selectively mediates the hydrogenolysis of aromatic alcohols, aldehydes, and ketones by using an ultralow catalytic amount (0.1 mol % Pd) under mild reaction conditions. The broad reaction scope as well as the catalyst's superior activity...

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Autores principales: Pandarus, Valerica, Ciriminna, Rosaria, Gingras, Geneviève, Béland, François, Pagliaro, Mario, Kaliaguine, Serge
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5754550/
https://www.ncbi.nlm.nih.gov/pubmed/29318100
http://dx.doi.org/10.1002/open.201700185
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author Pandarus, Valerica
Ciriminna, Rosaria
Gingras, Geneviève
Béland, François
Pagliaro, Mario
Kaliaguine, Serge
author_facet Pandarus, Valerica
Ciriminna, Rosaria
Gingras, Geneviève
Béland, François
Pagliaro, Mario
Kaliaguine, Serge
author_sort Pandarus, Valerica
collection PubMed
description The new spherical sol–gel hybrid material SiliaCat Pd(0) selectively mediates the hydrogenolysis of aromatic alcohols, aldehydes, and ketones by using an ultralow catalytic amount (0.1 mol % Pd) under mild reaction conditions. The broad reaction scope as well as the catalyst's superior activity and pronounced stability open the route to green and convenient reductive deoxygenation processes of primary synthetic relevance in chemical research as well as in the fine chemical and petrochemical industries.
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spelling pubmed-57545502018-01-09 Hydrogenolysis of C−O Chemical Bonds of Broad Scope Mediated by a New Spherical Sol–Gel Catalyst Pandarus, Valerica Ciriminna, Rosaria Gingras, Geneviève Béland, François Pagliaro, Mario Kaliaguine, Serge ChemistryOpen Full Papers The new spherical sol–gel hybrid material SiliaCat Pd(0) selectively mediates the hydrogenolysis of aromatic alcohols, aldehydes, and ketones by using an ultralow catalytic amount (0.1 mol % Pd) under mild reaction conditions. The broad reaction scope as well as the catalyst's superior activity and pronounced stability open the route to green and convenient reductive deoxygenation processes of primary synthetic relevance in chemical research as well as in the fine chemical and petrochemical industries. John Wiley and Sons Inc. 2017-12-11 /pmc/articles/PMC5754550/ /pubmed/29318100 http://dx.doi.org/10.1002/open.201700185 Text en © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial‐NoDerivs (http://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Full Papers
Pandarus, Valerica
Ciriminna, Rosaria
Gingras, Geneviève
Béland, François
Pagliaro, Mario
Kaliaguine, Serge
Hydrogenolysis of C−O Chemical Bonds of Broad Scope Mediated by a New Spherical Sol–Gel Catalyst
title Hydrogenolysis of C−O Chemical Bonds of Broad Scope Mediated by a New Spherical Sol–Gel Catalyst
title_full Hydrogenolysis of C−O Chemical Bonds of Broad Scope Mediated by a New Spherical Sol–Gel Catalyst
title_fullStr Hydrogenolysis of C−O Chemical Bonds of Broad Scope Mediated by a New Spherical Sol–Gel Catalyst
title_full_unstemmed Hydrogenolysis of C−O Chemical Bonds of Broad Scope Mediated by a New Spherical Sol–Gel Catalyst
title_short Hydrogenolysis of C−O Chemical Bonds of Broad Scope Mediated by a New Spherical Sol–Gel Catalyst
title_sort hydrogenolysis of c−o chemical bonds of broad scope mediated by a new spherical sol–gel catalyst
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5754550/
https://www.ncbi.nlm.nih.gov/pubmed/29318100
http://dx.doi.org/10.1002/open.201700185
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