From stable Sb- and Bi-centered radicals to a compound with a Ga=Sb double bond

Neutral stibinyl and bismuthinyl radicals are typically short-lived, reactive species. Here we show the synthesis and solid-state structures of two stable stibinyl [L(Cl)Ga](2)Sb· 1 and bismuthinyl radicals [L(I)Ga](2)Bi· 4, which are stabilized by electropositive metal centers. Their description as...

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Detalles Bibliográficos
Autores principales: Ganesamoorthy, Chelladurai, Helling, Christoph, Wölper, Christoph, Frank, Walter, Bill, Eckhard, Cutsail, George E., Schulz, Stephan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5758792/
https://www.ncbi.nlm.nih.gov/pubmed/29311607
http://dx.doi.org/10.1038/s41467-017-02581-2

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5758792/
https://www.ncbi.nlm.nih.gov/pubmed/29311607
http://dx.doi.org/10.1038/s41467-017-02581-2

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