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From stable Sb- and Bi-centered radicals to a compound with a Ga=Sb double bond
Neutral stibinyl and bismuthinyl radicals are typically short-lived, reactive species. Here we show the synthesis and solid-state structures of two stable stibinyl [L(Cl)Ga](2)Sb· 1 and bismuthinyl radicals [L(I)Ga](2)Bi· 4, which are stabilized by electropositive metal centers. Their description as...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5758792/ https://www.ncbi.nlm.nih.gov/pubmed/29311607 http://dx.doi.org/10.1038/s41467-017-02581-2 |