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Electrode initiated proton-coupled electron transfer to promote degradation of a nickel(ii) coordination complex
A Ni(ii) bisphosphine dithiolate compound degrades into an electrode-adsorbed film that can evolve hydrogen under reducing and protic conditions. An electrochemical study suggests that the degradation mechanism involves an initial concerted proton–electron transfer. The potential susceptibility of N...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5761499/ https://www.ncbi.nlm.nih.gov/pubmed/29403633 http://dx.doi.org/10.1039/c5sc00476d |