Electrode initiated proton-coupled electron transfer to promote degradation of a nickel(ii) coordination complex

A Ni(ii) bisphosphine dithiolate compound degrades into an electrode-adsorbed film that can evolve hydrogen under reducing and protic conditions. An electrochemical study suggests that the degradation mechanism involves an initial concerted proton–electron transfer. The potential susceptibility of N...

Descripción completa

Detalles Bibliográficos
Autores principales: McCarthy, Brian D., Donley, Carrie L., Dempsey, Jillian L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5761499/
https://www.ncbi.nlm.nih.gov/pubmed/29403633
http://dx.doi.org/10.1039/c5sc00476d
_version_ 1783291574681075712
author McCarthy, Brian D.
Donley, Carrie L.
Dempsey, Jillian L.
author_facet McCarthy, Brian D.
Donley, Carrie L.
Dempsey, Jillian L.
author_sort McCarthy, Brian D.
collection PubMed
description A Ni(ii) bisphosphine dithiolate compound degrades into an electrode-adsorbed film that can evolve hydrogen under reducing and protic conditions. An electrochemical study suggests that the degradation mechanism involves an initial concerted proton–electron transfer. The potential susceptibility of Ni–S bonds in molecular hydrogen evolution catalysts to degradation via C–S bond cleavage is discussed.
format Online
Article
Text
id pubmed-5761499
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-57614992018-02-05 Electrode initiated proton-coupled electron transfer to promote degradation of a nickel(ii) coordination complex McCarthy, Brian D. Donley, Carrie L. Dempsey, Jillian L. Chem Sci Chemistry A Ni(ii) bisphosphine dithiolate compound degrades into an electrode-adsorbed film that can evolve hydrogen under reducing and protic conditions. An electrochemical study suggests that the degradation mechanism involves an initial concerted proton–electron transfer. The potential susceptibility of Ni–S bonds in molecular hydrogen evolution catalysts to degradation via C–S bond cleavage is discussed. Royal Society of Chemistry 2015-05-01 2015-03-05 /pmc/articles/PMC5761499/ /pubmed/29403633 http://dx.doi.org/10.1039/c5sc00476d Text en This journal is © The Royal Society of Chemistry 2015 https://creativecommons.org/licenses/by-nc/3.0/This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0)
spellingShingle Chemistry
McCarthy, Brian D.
Donley, Carrie L.
Dempsey, Jillian L.
Electrode initiated proton-coupled electron transfer to promote degradation of a nickel(ii) coordination complex
title Electrode initiated proton-coupled electron transfer to promote degradation of a nickel(ii) coordination complex
title_full Electrode initiated proton-coupled electron transfer to promote degradation of a nickel(ii) coordination complex
title_fullStr Electrode initiated proton-coupled electron transfer to promote degradation of a nickel(ii) coordination complex
title_full_unstemmed Electrode initiated proton-coupled electron transfer to promote degradation of a nickel(ii) coordination complex
title_short Electrode initiated proton-coupled electron transfer to promote degradation of a nickel(ii) coordination complex
title_sort electrode initiated proton-coupled electron transfer to promote degradation of a nickel(ii) coordination complex
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5761499/
https://www.ncbi.nlm.nih.gov/pubmed/29403633
http://dx.doi.org/10.1039/c5sc00476d
work_keys_str_mv AT mccarthybriand electrodeinitiatedprotoncoupledelectrontransfertopromotedegradationofanickeliicoordinationcomplex
AT donleycarriel electrodeinitiatedprotoncoupledelectrontransfertopromotedegradationofanickeliicoordinationcomplex
AT dempseyjillianl electrodeinitiatedprotoncoupledelectrontransfertopromotedegradationofanickeliicoordinationcomplex

Ejemplares similares