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Electrode initiated proton-coupled electron transfer to promote degradation of a nickel(ii) coordination complex

A Ni(ii) bisphosphine dithiolate compound degrades into an electrode-adsorbed film that can evolve hydrogen under reducing and protic conditions. An electrochemical study suggests that the degradation mechanism involves an initial concerted proton–electron transfer. The potential susceptibility of N...

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Detalles Bibliográficos
Autores principales:	McCarthy, Brian D., Donley, Carrie L., Dempsey, Jillian L.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5761499/ https://www.ncbi.nlm.nih.gov/pubmed/29403633 http://dx.doi.org/10.1039/c5sc00476d

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