Enantioselective Rhodium‐Catalyzed Coupling of Arylboronic Acids, 1,3‐Enynes, and Imines by Alkenyl‐to‐Allyl 1,4‐Rhodium(I) Migration

A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3‐enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl‐to‐allyl 1,4‐rhodium(I) migration.

Detalles Bibliográficos
Autores principales: Callingham, Michael, Partridge, Benjamin M., Lewis, William, Lam, Hon Wai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5765452/
https://www.ncbi.nlm.nih.gov/pubmed/28980437
http://dx.doi.org/10.1002/anie.201709334

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5765452/
https://www.ncbi.nlm.nih.gov/pubmed/28980437
http://dx.doi.org/10.1002/anie.201709334

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