Enantioselective Rhodium‐Catalyzed Coupling of Arylboronic Acids, 1,3‐Enynes, and Imines by Alkenyl‐to‐Allyl 1,4‐Rhodium(I) Migration

A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3‐enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl‐to‐allyl 1,4‐rhodium(I) migration.

Detalles Bibliográficos
Autores principales: Callingham, Michael, Partridge, Benjamin M., Lewis, William, Lam, Hon Wai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5765452/
https://www.ncbi.nlm.nih.gov/pubmed/28980437
http://dx.doi.org/10.1002/anie.201709334
_version_ 1783292233959604224
author Callingham, Michael
Partridge, Benjamin M.
Lewis, William
Lam, Hon Wai
author_facet Callingham, Michael
Partridge, Benjamin M.
Lewis, William
Lam, Hon Wai
author_sort Callingham, Michael
collection PubMed
description A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3‐enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl‐to‐allyl 1,4‐rhodium(I) migration.
format Online
Article
Text
id pubmed-5765452
institution National Center for Biotechnology Information
language English
publishDate 2017
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-57654522018-02-01 Enantioselective Rhodium‐Catalyzed Coupling of Arylboronic Acids, 1,3‐Enynes, and Imines by Alkenyl‐to‐Allyl 1,4‐Rhodium(I) Migration Callingham, Michael Partridge, Benjamin M. Lewis, William Lam, Hon Wai Angew Chem Int Ed Engl Communications A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3‐enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl‐to‐allyl 1,4‐rhodium(I) migration. John Wiley and Sons Inc. 2017-11-24 2017-12-18 /pmc/articles/PMC5765452/ /pubmed/28980437 http://dx.doi.org/10.1002/anie.201709334 Text en © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution (http://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Callingham, Michael
Partridge, Benjamin M.
Lewis, William
Lam, Hon Wai
Enantioselective Rhodium‐Catalyzed Coupling of Arylboronic Acids, 1,3‐Enynes, and Imines by Alkenyl‐to‐Allyl 1,4‐Rhodium(I) Migration
title Enantioselective Rhodium‐Catalyzed Coupling of Arylboronic Acids, 1,3‐Enynes, and Imines by Alkenyl‐to‐Allyl 1,4‐Rhodium(I) Migration
title_full Enantioselective Rhodium‐Catalyzed Coupling of Arylboronic Acids, 1,3‐Enynes, and Imines by Alkenyl‐to‐Allyl 1,4‐Rhodium(I) Migration
title_fullStr Enantioselective Rhodium‐Catalyzed Coupling of Arylboronic Acids, 1,3‐Enynes, and Imines by Alkenyl‐to‐Allyl 1,4‐Rhodium(I) Migration
title_full_unstemmed Enantioselective Rhodium‐Catalyzed Coupling of Arylboronic Acids, 1,3‐Enynes, and Imines by Alkenyl‐to‐Allyl 1,4‐Rhodium(I) Migration
title_short Enantioselective Rhodium‐Catalyzed Coupling of Arylboronic Acids, 1,3‐Enynes, and Imines by Alkenyl‐to‐Allyl 1,4‐Rhodium(I) Migration
title_sort enantioselective rhodium‐catalyzed coupling of arylboronic acids, 1,3‐enynes, and imines by alkenyl‐to‐allyl 1,4‐rhodium(i) migration
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5765452/
https://www.ncbi.nlm.nih.gov/pubmed/28980437
http://dx.doi.org/10.1002/anie.201709334
work_keys_str_mv AT callinghammichael enantioselectiverhodiumcatalyzedcouplingofarylboronicacids13enynesandiminesbyalkenyltoallyl14rhodiumimigration
AT partridgebenjaminm enantioselectiverhodiumcatalyzedcouplingofarylboronicacids13enynesandiminesbyalkenyltoallyl14rhodiumimigration
AT lewiswilliam enantioselectiverhodiumcatalyzedcouplingofarylboronicacids13enynesandiminesbyalkenyltoallyl14rhodiumimigration
AT lamhonwai enantioselectiverhodiumcatalyzedcouplingofarylboronicacids13enynesandiminesbyalkenyltoallyl14rhodiumimigration

Ejemplares similares