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Oxidation of Vicinal Diols to α‐Hydroxy Ketones with H(2)O(2) and a Simple Manganese Catalyst

α‐Hydroxy ketones are valuable synthons in organic chemistry. Here we show that oxidation of vic‐diols to α‐hydroxy ketones with H(2)O(2) can be achieved with an in situ prepared catalyst based on manganese salts and pyridine‐2‐carboxylic acid. Furthermore the same catalyst is effective in alkene ep...

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Detalles Bibliográficos
Autores principales: Mecozzi, Francesco, Dong, Jia Jia, Saisaha, Pattama, Browne, Wesley R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5767754/
https://www.ncbi.nlm.nih.gov/pubmed/29398954
http://dx.doi.org/10.1002/ejoc.201701314