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Oxidation of Vicinal Diols to α‐Hydroxy Ketones with H(2)O(2) and a Simple Manganese Catalyst
α‐Hydroxy ketones are valuable synthons in organic chemistry. Here we show that oxidation of vic‐diols to α‐hydroxy ketones with H(2)O(2) can be achieved with an in situ prepared catalyst based on manganese salts and pyridine‐2‐carboxylic acid. Furthermore the same catalyst is effective in alkene ep...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5767754/ https://www.ncbi.nlm.nih.gov/pubmed/29398954 http://dx.doi.org/10.1002/ejoc.201701314 |