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Enantiospecific sp(2)–sp(3) Coupling of ortho‐ and para‐Phenols with Secondary and Tertiary Boronic Esters

The coupling of ortho‐ and para‐phenols with secondary and tertiary boronic esters has been explored. In the case of para‐substituted phenols, after reaction of a dilithio phenolate species with a boronic ester, treatment with Ph(3)BiF(2) or Martin's sulfurane gave the coupled product with comp...

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Detalles Bibliográficos
Autores principales: Wilson, Claire M., Ganesh, Venkataraman, Noble, Adam, Aggarwal, Varinder K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5767764/
https://www.ncbi.nlm.nih.gov/pubmed/29111609
http://dx.doi.org/10.1002/anie.201710777