Radical asymmetric intramolecular α-cyclopropanation of aldehydes towards bicyclo[3.1.0]hexanes containing vicinal all-carbon quaternary stereocenters

The development of a general catalytic method for the direct and stereoselective construction of cyclopropanes bearing highly congested vicinal all-carbon quaternary stereocenters remains a formidable challenge in chemical synthesis. Here, we report an intramolecular radical cyclopropanation of unac...

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Detalles Bibliográficos
Autores principales: Ye, Liu, Gu, Qiang-Shuai, Tian, Yu, Meng, Xiang, Chen, Guo-Cong, Liu, Xin-Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5768789/
https://www.ncbi.nlm.nih.gov/pubmed/29335407
http://dx.doi.org/10.1038/s41467-017-02231-7

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5768789/
https://www.ncbi.nlm.nih.gov/pubmed/29335407
http://dx.doi.org/10.1038/s41467-017-02231-7

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