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Ruthenium PNN(O) Complexes: Cooperative Reactivity and Application as Catalysts for Acceptorless Dehydrogenative Coupling Reactions

[Image: see text] The novel tridentate PNN(OH) pincer ligand L(H) features a reactive 2-hydroxypyridine functionality as well as a bipyridyl-methylphosphine skeleton for meridional coordination. This proton-responsive ligand coordinates in a straightforward manner to RuCl(CO)(H)(PPh(3))(3) to genera...

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Detalles Bibliográficos
Autores principales: de Boer, Sandra Y., Korstanje, Ties J., La Rooij, Stefan R., Kox, Rogier, Reek, Joost N. H., van der Vlugt, Jarl Ivar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5770139/
https://www.ncbi.nlm.nih.gov/pubmed/29353952
http://dx.doi.org/10.1021/acs.organomet.7b00111