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Crystal structures of bis­[4-(di­methyl­amino)­pyridinium] tetra­kis­(thio­cyanato-κN)manganate(II) and tris­[4-(di­methyl­amino)­pyridinium] penta­kis(thio­cyanato-κN)manganate(II)

The crystal structures of the title salts, (C(7)H(11)N(2))(2)[Mn(NCS)(4)] (1) and (C(7)H(11)N(2))(3)[Mn(NCS)(5)] (2), consist of manganese(II) cations that are tetra­hedrally (1) or trigonal–bipyramidally (2) coordinated to four or five terminal N-bonded thio­cyanate ligands, respectively, into disc...

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Detalles Bibliográficos
Autores principales: Neumann, Tristan, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5778477/
https://www.ncbi.nlm.nih.gov/pubmed/29416883
http://dx.doi.org/10.1107/S2056989017017510