Crystal structure of the η(4)-ketimine titanium complex (di­phenyl­amido-κN){3-methyl-6-[(4-methyl­phen­yl)(phenyl­aza­nid­yl)methyl­idene]cyclo­hexa-2,4-dien-1-yl-κ(2) N,C (1)}(η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(IV)

The mol­ecular structure of the title titanium(IV) half-sandwich complex, [Ti(η(5)-C(10)H(15))(η(4)-C(21)H(19)N)(C(12)H(10)N)], shows a three-legged piano-stool geometry at the central Ti(IV) atom, comprising of one penta­methyl­cyclo­penta­dienyl ligand, one bidentate ketimine ligand in an η(4)-coo...

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Detalles Bibliográficos
Autores principales: Fischer, Malte, Schmidtmann, Marc, Beckhaus, Rüdiger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5778480/
https://www.ncbi.nlm.nih.gov/pubmed/29416886
http://dx.doi.org/10.1107/S2056989017017455

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5778480/
https://www.ncbi.nlm.nih.gov/pubmed/29416886
http://dx.doi.org/10.1107/S2056989017017455

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