Crystal structure of the η(4)-ketimine titanium complex (di­phenyl­amido-κN){3-methyl-6-[(4-methyl­phen­yl)(phenyl­aza­nid­yl)methyl­idene]cyclo­hexa-2,4-dien-1-yl-κ(2) N,C (1)}(η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(IV)

The mol­ecular structure of the title titanium(IV) half-sandwich complex, [Ti(η(5)-C(10)H(15))(η(4)-C(21)H(19)N)(C(12)H(10)N)], shows a three-legged piano-stool geometry at the central Ti(IV) atom, comprising of one penta­methyl­cyclo­penta­dienyl ligand, one bidentate ketimine ligand in an η(4)-coo...

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Detalles Bibliográficos
Autores principales: Fischer, Malte, Schmidtmann, Marc, Beckhaus, Rüdiger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5778480/
https://www.ncbi.nlm.nih.gov/pubmed/29416886
http://dx.doi.org/10.1107/S2056989017017455
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author Fischer, Malte
Schmidtmann, Marc
Beckhaus, Rüdiger
author_facet Fischer, Malte
Schmidtmann, Marc
Beckhaus, Rüdiger
author_sort Fischer, Malte
collection PubMed
description The mol­ecular structure of the title titanium(IV) half-sandwich complex, [Ti(η(5)-C(10)H(15))(η(4)-C(21)H(19)N)(C(12)H(10)N)], shows a three-legged piano-stool geometry at the central Ti(IV) atom, comprising of one penta­methyl­cyclo­penta­dienyl ligand, one bidentate ketimine ligand in an η(4)-coordination mode and one monodentate di­phenyl­amide ligand. Except for van der Waals forces, there are no significant inter­molecular inter­actions in the crystal.
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spelling pubmed-57784802018-02-07 Crystal structure of the η(4)-ketimine titanium complex (di­phenyl­amido-κN){3-methyl-6-[(4-methyl­phen­yl)(phenyl­aza­nid­yl)methyl­idene]cyclo­hexa-2,4-dien-1-yl-κ(2) N,C (1)}(η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(IV) Fischer, Malte Schmidtmann, Marc Beckhaus, Rüdiger Acta Crystallogr E Crystallogr Commun Research Communications The mol­ecular structure of the title titanium(IV) half-sandwich complex, [Ti(η(5)-C(10)H(15))(η(4)-C(21)H(19)N)(C(12)H(10)N)], shows a three-legged piano-stool geometry at the central Ti(IV) atom, comprising of one penta­methyl­cyclo­penta­dienyl ligand, one bidentate ketimine ligand in an η(4)-coordination mode and one monodentate di­phenyl­amide ligand. Except for van der Waals forces, there are no significant inter­molecular inter­actions in the crystal. International Union of Crystallography 2018-01-01 /pmc/articles/PMC5778480/ /pubmed/29416886 http://dx.doi.org/10.1107/S2056989017017455 Text en © Fischer et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Fischer, Malte
Schmidtmann, Marc
Beckhaus, Rüdiger
Crystal structure of the η(4)-ketimine titanium complex (di­phenyl­amido-κN){3-methyl-6-[(4-methyl­phen­yl)(phenyl­aza­nid­yl)methyl­idene]cyclo­hexa-2,4-dien-1-yl-κ(2) N,C (1)}(η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(IV)
title Crystal structure of the η(4)-ketimine titanium complex (di­phenyl­amido-κN){3-methyl-6-[(4-methyl­phen­yl)(phenyl­aza­nid­yl)methyl­idene]cyclo­hexa-2,4-dien-1-yl-κ(2) N,C (1)}(η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(IV)
title_full Crystal structure of the η(4)-ketimine titanium complex (di­phenyl­amido-κN){3-methyl-6-[(4-methyl­phen­yl)(phenyl­aza­nid­yl)methyl­idene]cyclo­hexa-2,4-dien-1-yl-κ(2) N,C (1)}(η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(IV)
title_fullStr Crystal structure of the η(4)-ketimine titanium complex (di­phenyl­amido-κN){3-methyl-6-[(4-methyl­phen­yl)(phenyl­aza­nid­yl)methyl­idene]cyclo­hexa-2,4-dien-1-yl-κ(2) N,C (1)}(η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(IV)
title_full_unstemmed Crystal structure of the η(4)-ketimine titanium complex (di­phenyl­amido-κN){3-methyl-6-[(4-methyl­phen­yl)(phenyl­aza­nid­yl)methyl­idene]cyclo­hexa-2,4-dien-1-yl-κ(2) N,C (1)}(η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(IV)
title_short Crystal structure of the η(4)-ketimine titanium complex (di­phenyl­amido-κN){3-methyl-6-[(4-methyl­phen­yl)(phenyl­aza­nid­yl)methyl­idene]cyclo­hexa-2,4-dien-1-yl-κ(2) N,C (1)}(η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(IV)
title_sort crystal structure of the η(4)-ketimine titanium complex (di­phenyl­amido-κn){3-methyl-6-[(4-methyl­phen­yl)(phenyl­aza­nid­yl)methyl­idene]cyclo­hexa-2,4-dien-1-yl-κ(2) n,c (1)}(η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(iv)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5778480/
https://www.ncbi.nlm.nih.gov/pubmed/29416886
http://dx.doi.org/10.1107/S2056989017017455
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