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Crystal structure of the η(4)-ketimine titanium complex (diphenylamido-κN){3-methyl-6-[(4-methylphenyl)(phenylazanidyl)methylidene]cyclohexa-2,4-dien-1-yl-κ(2) N,C (1)}(η(5)-pentamethylcyclopentadienyl)titanium(IV)
The molecular structure of the title titanium(IV) half-sandwich complex, [Ti(η(5)-C(10)H(15))(η(4)-C(21)H(19)N)(C(12)H(10)N)], shows a three-legged piano-stool geometry at the central Ti(IV) atom, comprising of one pentamethylcyclopentadienyl ligand, one bidentate ketimine ligand in an η(4)-coo...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5778480/ https://www.ncbi.nlm.nih.gov/pubmed/29416886 http://dx.doi.org/10.1107/S2056989017017455 |