Chirality recognition of winding vine-shaped heterobiaryls with molecular asymmetry. Kinetic and dynamic kinetic resolution by Shi’s asymmetric epoxidation

The chirality of winding vine-shaped heterobiaryls with molecular asymmetry is recognized by a sugar-based chiral oxidant. Kinetic resolution of (±)-bisbenzoimidazole bearing an olefin moiety takes place with Shi’s asymmetric epoxidation to observe k(rel) value up to ca. 35 affording the correspondi...

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Detalles Bibliográficos
Autores principales: Maruhashi, Kazuki, Okayama, Yoichi, Inoue, Ryo, Ashida, Shiomi, Toyomori, Yuka, Okano, Kentaro, Mori, Atsunori
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5786050/
https://www.ncbi.nlm.nih.gov/pubmed/29374202
http://dx.doi.org/10.1038/s41598-018-19878-x

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5786050/
https://www.ncbi.nlm.nih.gov/pubmed/29374202
http://dx.doi.org/10.1038/s41598-018-19878-x

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