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A gel aging effect in the synthesis of open-framework gallium phosphates: structure solution and solid-state NMR of a large-pore, open-framework material

The templated zeolite-analogue GaPO-34 (CHA structure type) crystallises from a gel precursor Ga(2)O(3) : 2H(3)PO(4) : 1HF : 1.7SDA : 70H(2)O (where SDA = structure directing agent), treated hydrothermally for 24 hours at 170 °C using either pyridine or 1-methylimizadole as SDA and one of either poo...

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Detalles Bibliográficos
Autores principales: Broom, Lucy K., Clarkson, Guy J., Guillou, Nathalie, Hooper, Joseph E., Dawson, Daniel M., Tang, Chiu C., Ashbrook, Sharon E., Walton, Richard I.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5789431/
https://www.ncbi.nlm.nih.gov/pubmed/29171855
http://dx.doi.org/10.1039/c7dt03709k