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Molecular chirality: A new approach from a dynamical point of view
The double minimum potential (DMP), which Hund assumed to explain the quantum-mechanical stability of enantiomers, was discussed, by citing three typical examples of DMP: inversion, internal rotation, and puckering. They expanded the classical scope of chirality, as defined by Kelvin, and indicated...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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The Japan Academy
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5790761/ https://www.ncbi.nlm.nih.gov/pubmed/29225310 http://dx.doi.org/10.2183/pjab.93.053 |