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Magnetic Nature of the Cr(III)–Ln(III) Interactions in [Cr(III) (2)Ln(III) (3)] Clusters with Slow Magnetic Relaxation

Two 3d‐4f hetero‐metal pentanuclear complexes with the formula {[Cr(III) (2)Ln(III) (3)L(10)(OH)(6)(H(2)O)(2)]Et(3)NH} [Ln=Tb (1), Dy (2); HL=pivalic acid, Et(3)N=triethylamine] have been produced. The metal core of each cluster is made up of a trigonal bipyramid with three Ln(III) ions (plane) and...

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Detalles Bibliográficos
Autores principales: Zhao, Xiao‐Qing, Xiang, Shuo, Wang, Jin, Bao, Dong‐Xu, Li, Yun‐Chun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5795553/
https://www.ncbi.nlm.nih.gov/pubmed/29435404
http://dx.doi.org/10.1002/open.201700165