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Visible light sensitizer-catalyzed highly selective photo oxidation from thioethers into sulfoxides under aerobic condition
We report herein a visible light sensitizer-catalyzed aerobic oxidation of thioethers, affording sulfoxides in good to excellent yields. The loading of the catalyst was as low as 0.1 mol%. The selectivity was excellent. Mechanism studies showed both singlet oxygen and superoxide radical anion were l...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5797238/ https://www.ncbi.nlm.nih.gov/pubmed/29396475 http://dx.doi.org/10.1038/s41598-018-20631-7 |