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A series of tetraazalene radical-bridged M(2) (M = Cr(III), Mn(II), Fe(II), Co(II)) complexes with strong magnetic exchange coupling

The ability of tetraazalene radical bridging ligands to mediate exceptionally strong magnetic exchange coupling across a range of transition metal complexes is demonstrated. The redox-active bridging ligand N,N′,N′′,N′′′-tetra(2-methylphenyl)-2,5-diamino-1,4-diiminobenzoquinone ((NMePh)LH(2)) was me...

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Detalles Bibliográficos
Autores principales: DeGayner, Jordan A., Jeon, Ie-Rang, Harris, T. David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5802272/
https://www.ncbi.nlm.nih.gov/pubmed/29435213
http://dx.doi.org/10.1039/c5sc02725j